# Electronic Supplementary Material (ESI) for Catalysis Science & Technology. # This journal is © The Royal Society of Chemistry 2015 ####################################################################### # # This file contains crystal structure data downloaded from the # Cambridge Structural Database (CSD) hosted by the Cambridge # Crystallographic Data Centre (CCDC). # # Full information about CCDC data access policies and citation # guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 # # Audit and citation data items may have been added by the CCDC. # Please retain this information to preserve the provenance of # this file and to allow appropriate attribution of the data. # ####################################################################### data_l0492a _database_code_depnum_ccdc_archive 'CCDC 1422009' _audit_update_record ; 2015-09-02 deposited with the CCDC. 2015-11-10 downloaded from the CCDC. ; _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C45 H62 N2 O2 P2 Rh2 S2' _chemical_formula_sum 'C45 H62 N2 O2 P2 Rh2 S2' _chemical_formula_weight 994.85 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M 'P 21/n' _symmetry_space_group_name_Hall '-P 2yn' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' _cell_length_a 12.7487(4) _cell_length_b 19.7725(6) _cell_length_c 18.4361(5) _cell_angle_alpha 90.00 _cell_angle_beta 103.046(1) _cell_angle_gamma 90.00 _cell_volume 4527.3(2) _cell_formula_units_Z 4 _cell_measurement_temperature 150(2) _cell_measurement_reflns_used 40473 _cell_measurement_theta_min 1.53 _cell_measurement_theta_max 27.50 _exptl_crystal_description block _exptl_crystal_colour yellow _exptl_crystal_size_max 0.25 _exptl_crystal_size_mid 0.19 _exptl_crystal_size_min 0.09 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.460 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2056 _exptl_absorpt_coefficient_mu 0.930 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.6688 _exptl_absorpt_correction_T_max 0.7456 _exptl_absorpt_process_details SADABS-2012/1 _exptl_special_details ; ? ; _diffrn_ambient_temperature 150(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker Kappa ApexII' _diffrn_measurement_method '\f and \w scans' _diffrn_detector_area_resol_mean ? _diffrn_reflns_number 60826 _diffrn_reflns_av_R_equivalents 0.0386 _diffrn_reflns_av_sigmaI/netI 0.0300 _diffrn_reflns_limit_h_min -16 _diffrn_reflns_limit_h_max 16 _diffrn_reflns_limit_k_min -25 _diffrn_reflns_limit_k_max 25 _diffrn_reflns_limit_l_min -23 _diffrn_reflns_limit_l_max 23 _diffrn_reflns_theta_min 1.53 _diffrn_reflns_theta_max 27.50 _reflns_number_total 10392 _reflns_number_gt 8330 _reflns_threshold_expression I>2\s(I) _computing_data_collection Apex2 _computing_cell_refinement Peakref _computing_data_reduction 'Eval15, SADABS-2012/1' _computing_structure_solution 'SHELXT (Sheldrick, 2012)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 2008)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0263P)^2^+1.0759P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens difmap _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 10392 _refine_ls_number_parameters 508 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0396 _refine_ls_R_factor_gt 0.0255 _refine_ls_wR_factor_ref 0.0580 _refine_ls_wR_factor_gt 0.0542 _refine_ls_goodness_of_fit_ref 1.023 _refine_ls_restrained_S_all 1.023 _refine_ls_shift/su_max 0.003 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Rh1 Rh 0.485597(13) 0.437719(7) 0.223408(9) 0.02444(4) Uani 1 1 d . . . P1 P 0.61524(4) 0.41166(2) 0.15775(3) 0.02301(11) Uani 1 1 d . . . O1 O 0.56811(17) 0.35014(10) 0.35463(10) 0.0661(6) Uani 1 1 d . . . N1 N 0.78578(13) 0.55620(8) 0.09976(9) 0.0250(4) Uani 1 1 d . . . C11 C 0.69320(15) 0.54194(9) 0.11966(10) 0.0241(4) Uani 1 1 d . . . C21 C 0.64662(17) 0.58630(10) 0.16193(12) 0.0314(5) Uani 1 1 d . . . H21 H 0.5826 0.5743 0.1771 0.038 Uiso 1 1 calc R . . C31 C 0.69506(18) 0.64775(11) 0.18127(13) 0.0383(5) Uani 1 1 d . . . H31 H 0.6642 0.6792 0.2093 0.046 Uiso 1 1 calc R . . C41 C 0.78886(18) 0.66339(11) 0.15966(13) 0.0379(5) Uani 1 1 d . . . H41 H 0.8223 0.7061 0.1717 0.045 Uiso 1 1 calc R . . C51 C 0.83402(16) 0.61614(10) 0.12008(11) 0.0267(4) Uani 1 1 d . . . C61 C 0.93657(15) 0.62975(10) 0.09676(11) 0.0275(4) Uani 1 1 d . . . C71 C 1.00517(17) 0.68178(11) 0.12893(13) 0.0383(5) Uani 1 1 d . . . H71 H 0.9877 0.7083 0.1675 0.046 Uiso 1 1 calc R . . C81 C 1.09878(19) 0.69517(13) 0.10504(14) 0.0462(6) Uani 1 1 d . . . H81 H 1.1447 0.7309 0.1273 0.055 Uiso 1 1 calc R . . C91 C 1.12541(18) 0.65768(13) 0.05004(14) 0.0453(6) Uani 1 1 d . . . H91 H 1.1897 0.6671 0.0341 0.054 Uiso 1 1 calc R . . C101 C 1.05857(18) 0.60575(13) 0.01745(14) 0.0440(6) Uani 1 1 d . . . H101 H 1.0765 0.5798 -0.0214 0.053 Uiso 1 1 calc R . . C111 C 0.96528(17) 0.59157(11) 0.04143(12) 0.0342(5) Uani 1 1 d . . . H111 H 0.9205 0.5552 0.0195 0.041 Uiso 1 1 calc R . . C121 C 0.63917(16) 0.47647(9) 0.09022(11) 0.0257(4) Uani 1 1 d . . . H12A H 0.6832 0.4552 0.0586 0.031 Uiso 1 1 calc R . . H12B H 0.5686 0.4879 0.0574 0.031 Uiso 1 1 calc R . . C131 C 0.75529(16) 0.39375(10) 0.21491(12) 0.0311(5) Uani 1 1 d . . . C141 C 0.76005(19) 0.32360(11) 0.25154(14) 0.0425(6) Uani 1 1 d . . . H14A H 0.7523 0.2885 0.2131 0.064 Uiso 1 1 calc R . . H14B H 0.7015 0.3194 0.2777 0.064 Uiso 1 1 calc R . . H14C H 0.8294 0.3181 0.2871 0.064 Uiso 1 1 calc R . . C151 C 0.84409(17) 0.39762(11) 0.17085(14) 0.0394(5) Uani 1 1 d . . . H15A H 0.8451 0.4430 0.1496 0.059 Uiso 1 1 calc R . . H15B H 0.8298 0.3642 0.1306 0.059 Uiso 1 1 calc R . . H15C H 0.9140 0.3882 0.2042 0.059 Uiso 1 1 calc R . . C161 C 0.78021(18) 0.44734(11) 0.27723(12) 0.0376(5) Uani 1 1 d . . . H16A H 0.8518 0.4389 0.3088 0.056 Uiso 1 1 calc R . . H16B H 0.7262 0.4447 0.3074 0.056 Uiso 1 1 calc R . . H16C H 0.7785 0.4925 0.2550 0.056 Uiso 1 1 calc R . . C171 C 0.56537(16) 0.33802(10) 0.09310(12) 0.0296(5) Uani 1 1 d . . . C181 C 0.47386(18) 0.36477(11) 0.03024(12) 0.0385(5) Uani 1 1 d . . . H18A H 0.5042 0.3932 -0.0035 0.058 Uiso 1 1 calc R . . H18B H 0.4238 0.3916 0.0517 0.058 Uiso 1 1 calc R . . H18C H 0.4353 0.3266 0.0025 0.058 Uiso 1 1 calc R . . C191 C 0.64922(19) 0.30617(11) 0.05622(14) 0.0420(6) Uani 1 1 d . . . H19A H 0.7054 0.2846 0.0943 0.063 Uiso 1 1 calc R . . H19B H 0.6815 0.3413 0.0308 0.063 Uiso 1 1 calc R . . H19C H 0.6145 0.2722 0.0200 0.063 Uiso 1 1 calc R . . C201 C 0.51731(19) 0.28351(11) 0.13577(13) 0.0405(6) Uani 1 1 d . . . H20A H 0.4858 0.2473 0.1014 0.061 Uiso 1 1 calc R . . H20B H 0.4613 0.3038 0.1575 0.061 Uiso 1 1 calc R . . H20C H 0.5742 0.2648 0.1755 0.061 Uiso 1 1 calc R . . C211 C 0.5418(2) 0.38318(11) 0.30266(13) 0.0395(5) Uani 1 1 d . . . Rh2 Rh 0.381565(12) 0.576010(8) 0.240072(9) 0.02476(4) Uani 1 1 d . . . P2 P 0.39799(4) 0.62776(3) 0.35475(3) 0.02673(12) Uani 1 1 d . . . O2 O 0.40286(18) 0.69926(10) 0.15443(13) 0.0784(7) Uani 1 1 d . . . N2 N 0.14921(13) 0.59607(8) 0.44704(9) 0.0279(4) Uani 1 1 d . . . C12 C 0.19913(16) 0.58554(10) 0.39143(11) 0.0279(4) Uani 1 1 d . . . C22 C 0.14319(17) 0.57219(11) 0.31923(12) 0.0331(5) Uani 1 1 d . . . H22 H 0.1808 0.5659 0.2807 0.040 Uiso 1 1 calc R . . C32 C 0.03185(17) 0.56813(11) 0.30382(12) 0.0358(5) Uani 1 1 d . . . H32 H -0.0080 0.5589 0.2547 0.043 Uiso 1 1 calc R . . C42 C -0.02019(17) 0.57776(11) 0.36106(12) 0.0332(5) Uani 1 1 d . . . H42 H -0.0964 0.5748 0.3521 0.040 Uiso 1 1 calc R . . C52 C 0.04060(16) 0.59187(10) 0.43184(12) 0.0277(4) Uani 1 1 d . . . C62 C -0.01050(16) 0.60466(10) 0.49515(12) 0.0295(5) Uani 1 1 d . . . C72 C -0.10192(17) 0.56954(11) 0.50286(13) 0.0361(5) Uani 1 1 d . . . H72 H -0.1318 0.5357 0.4677 0.043 Uiso 1 1 calc R . . C82 C -0.14961(19) 0.58387(13) 0.56179(14) 0.0447(6) Uani 1 1 d . . . H82 H -0.2109 0.5589 0.5675 0.054 Uiso 1 1 calc R . . C92 C -0.1085(2) 0.63395(14) 0.61184(14) 0.0482(6) Uani 1 1 d . . . H92 H -0.1426 0.6446 0.6512 0.058 Uiso 1 1 calc R . . C102 C -0.01794(19) 0.66856(13) 0.60475(13) 0.0477(6) Uani 1 1 d . . . H102 H 0.0105 0.7031 0.6394 0.057 Uiso 1 1 calc R . . C112 C 0.03202(17) 0.65349(11) 0.54770(12) 0.0361(5) Uani 1 1 d . . . H112 H 0.0960 0.6767 0.5443 0.043 Uiso 1 1 calc R . . C122 C 0.32124(15) 0.58455(11) 0.41478(11) 0.0299(5) Uani 1 1 d . . . H12C H 0.3445 0.5367 0.4194 0.036 Uiso 1 1 calc R . . H12D H 0.3424 0.6048 0.4651 0.036 Uiso 1 1 calc R . . C132 C 0.35419(17) 0.71914(11) 0.35894(14) 0.0379(5) Uani 1 1 d . . . C142 C 0.24972(18) 0.72876(12) 0.29878(15) 0.0467(6) Uani 1 1 d . . . H14D H 0.1934 0.6993 0.3097 0.070 Uiso 1 1 calc R . . H14E H 0.2628 0.7171 0.2499 0.070 Uiso 1 1 calc R . . H14F H 0.2265 0.7760 0.2984 0.070 Uiso 1 1 calc R . . C152 C 0.33059(19) 0.73869(12) 0.43441(14) 0.0507(7) Uani 1 1 d . . . H15D H 0.3104 0.7865 0.4336 0.076 Uiso 1 1 calc R . . H15E H 0.3950 0.7311 0.4740 0.076 Uiso 1 1 calc R . . H15F H 0.2713 0.7109 0.4437 0.076 Uiso 1 1 calc R . . C162 C 0.43968(19) 0.76770(11) 0.34091(16) 0.0515(7) Uani 1 1 d . . . H16D H 0.4576 0.7539 0.2941 0.077 Uiso 1 1 calc R . . H16E H 0.5046 0.7661 0.3812 0.077 Uiso 1 1 calc R . . H16F H 0.4111 0.8139 0.3360 0.077 Uiso 1 1 calc R . . C172 C 0.54164(15) 0.61664(11) 0.40957(12) 0.0316(5) Uani 1 1 d . . . C182 C 0.56264(17) 0.54022(11) 0.41848(12) 0.0364(5) Uani 1 1 d . . . H18D H 0.5475 0.5188 0.3693 0.055 Uiso 1 1 calc R . . H18E H 0.5158 0.5207 0.4485 0.055 Uiso 1 1 calc R . . H18F H 0.6381 0.5324 0.4434 0.055 Uiso 1 1 calc R . . C192 C 0.56536(18) 0.64970(14) 0.48672(13) 0.0519(7) Uani 1 1 d . . . H19D H 0.6383 0.6376 0.5137 0.078 Uiso 1 1 calc R . . H19E H 0.5132 0.6337 0.5146 0.078 Uiso 1 1 calc R . . H19F H 0.5598 0.6990 0.4812 0.078 Uiso 1 1 calc R . . C202 C 0.62063(17) 0.64358(12) 0.36434(14) 0.0422(6) Uani 1 1 d . . . H20D H 0.6100 0.6924 0.3566 0.063 Uiso 1 1 calc R . . H20E H 0.6075 0.6206 0.3160 0.063 Uiso 1 1 calc R . . H20F H 0.6947 0.6349 0.3916 0.063 Uiso 1 1 calc R . . C212 C 0.39870(19) 0.65320(12) 0.19148(14) 0.0426(6) Uani 1 1 d . . . S13 S 0.38845(4) 0.51336(3) 0.13080(3) 0.02862(11) Uani 1 1 d . . . S23 S 0.34755(4) 0.46667(3) 0.28572(3) 0.02911(11) Uani 1 1 d . . . C13 C 0.25748(17) 0.47221(13) 0.09892(12) 0.0414(6) Uani 1 1 d . . . H13A H 0.2208 0.4930 0.0510 0.050 Uiso 1 1 calc R . . H13B H 0.2698 0.4240 0.0892 0.050 Uiso 1 1 calc R . . C23 C 0.18266(17) 0.47612(13) 0.15211(13) 0.0420(6) Uani 1 1 d . . . H23A H 0.1114 0.4581 0.1268 0.050 Uiso 1 1 calc R . . H23B H 0.1729 0.5242 0.1640 0.050 Uiso 1 1 calc R . . C33 C 0.22216(18) 0.43760(11) 0.22448(13) 0.0385(5) Uani 1 1 d . . . H33A H 0.2316 0.3896 0.2120 0.046 Uiso 1 1 calc R . . H33B H 0.1649 0.4392 0.2529 0.046 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Rh1 0.02957(9) 0.02171(8) 0.02317(8) 0.00052(6) 0.00836(6) -0.00196(6) P1 0.0261(3) 0.0181(2) 0.0249(3) 0.0002(2) 0.0060(2) -0.00162(19) O1 0.0926(15) 0.0634(13) 0.0492(11) 0.0322(10) 0.0301(11) 0.0259(11) N1 0.0261(9) 0.0232(8) 0.0253(9) 0.0023(7) 0.0052(7) -0.0008(7) C11 0.0282(10) 0.0219(10) 0.0218(10) 0.0019(8) 0.0049(8) -0.0004(8) C21 0.0293(11) 0.0287(11) 0.0388(12) -0.0006(9) 0.0130(10) -0.0017(9) C31 0.0417(13) 0.0258(11) 0.0532(15) -0.0086(10) 0.0230(12) -0.0034(9) C41 0.0420(13) 0.0235(11) 0.0518(15) -0.0082(10) 0.0184(11) -0.0095(9) C51 0.0271(10) 0.0255(10) 0.0273(11) 0.0024(8) 0.0055(9) -0.0039(8) C61 0.0254(10) 0.0278(11) 0.0284(11) 0.0057(8) 0.0039(9) -0.0021(8) C71 0.0361(12) 0.0408(13) 0.0372(13) -0.0023(10) 0.0069(10) -0.0123(10) C81 0.0383(14) 0.0515(15) 0.0468(15) 0.0031(12) 0.0050(12) -0.0184(11) C91 0.0282(12) 0.0599(16) 0.0496(15) 0.0127(13) 0.0128(11) -0.0076(11) C101 0.0359(13) 0.0574(16) 0.0423(14) 0.0029(12) 0.0166(11) 0.0031(11) C111 0.0294(11) 0.0364(12) 0.0365(12) 0.0014(10) 0.0066(10) -0.0032(9) C121 0.0292(10) 0.0232(10) 0.0263(10) -0.0008(8) 0.0096(8) -0.0030(8) C131 0.0284(11) 0.0248(10) 0.0371(12) 0.0020(9) 0.0014(9) 0.0011(8) C141 0.0447(14) 0.0287(12) 0.0495(15) 0.0069(11) 0.0007(11) 0.0058(10) C151 0.0261(11) 0.0345(12) 0.0565(15) 0.0012(11) 0.0069(11) 0.0036(9) C161 0.0368(13) 0.0308(11) 0.0380(13) -0.0004(10) -0.0069(10) -0.0008(9) C171 0.0333(11) 0.0232(10) 0.0344(12) -0.0049(9) 0.0122(9) -0.0059(8) C181 0.0410(13) 0.0374(12) 0.0343(12) -0.0092(10) 0.0028(10) -0.0091(10) C191 0.0469(14) 0.0323(12) 0.0502(15) -0.0126(11) 0.0179(12) -0.0047(10) C201 0.0508(14) 0.0280(11) 0.0448(14) -0.0052(10) 0.0148(11) -0.0147(10) C211 0.0536(15) 0.0333(12) 0.0363(13) 0.0039(10) 0.0202(11) 0.0038(11) Rh2 0.02293(8) 0.02348(8) 0.02774(9) 0.00148(6) 0.00547(6) -0.00105(6) P2 0.0206(3) 0.0246(3) 0.0340(3) -0.0038(2) 0.0041(2) -0.0003(2) O2 0.1057(17) 0.0417(11) 0.0959(17) 0.0304(11) 0.0400(14) 0.0009(11) N2 0.0241(9) 0.0266(9) 0.0327(10) -0.0037(7) 0.0059(7) 0.0001(7) C12 0.0234(10) 0.0278(10) 0.0323(11) -0.0037(9) 0.0056(9) -0.0005(8) C22 0.0296(11) 0.0389(12) 0.0315(11) -0.0052(9) 0.0082(9) -0.0018(9) C32 0.0307(12) 0.0414(13) 0.0322(12) -0.0051(10) 0.0005(9) -0.0045(9) C42 0.0233(10) 0.0357(12) 0.0395(12) -0.0036(10) 0.0043(9) -0.0022(9) C52 0.0249(10) 0.0221(10) 0.0358(12) -0.0006(8) 0.0064(9) 0.0002(8) C62 0.0233(10) 0.0292(11) 0.0350(12) 0.0029(9) 0.0047(9) 0.0085(8) C72 0.0303(12) 0.0339(12) 0.0452(14) 0.0050(10) 0.0108(10) 0.0063(9) C82 0.0351(13) 0.0514(15) 0.0523(15) 0.0180(13) 0.0194(12) 0.0150(11) C92 0.0457(15) 0.0630(17) 0.0373(14) 0.0072(13) 0.0127(12) 0.0269(13) C102 0.0415(14) 0.0573(16) 0.0408(14) -0.0104(12) 0.0022(11) 0.0213(12) C112 0.0271(11) 0.0391(12) 0.0395(13) -0.0033(10) 0.0021(10) 0.0096(9) C122 0.0223(10) 0.0362(12) 0.0308(11) -0.0048(9) 0.0053(9) -0.0008(8) C132 0.0271(11) 0.0277(11) 0.0570(15) -0.0077(10) 0.0050(11) 0.0017(9) C142 0.0334(13) 0.0312(12) 0.0718(18) -0.0012(12) 0.0036(12) 0.0071(10) C152 0.0380(14) 0.0404(14) 0.0709(18) -0.0243(13) 0.0062(13) 0.0045(11) C162 0.0380(13) 0.0240(12) 0.089(2) -0.0018(12) 0.0074(13) -0.0003(10) C172 0.0191(10) 0.0366(12) 0.0370(12) -0.0057(10) 0.0020(9) 0.0013(8) C182 0.0261(11) 0.0436(13) 0.0375(13) 0.0038(10) 0.0026(10) 0.0052(9) C192 0.0318(13) 0.0693(18) 0.0488(15) -0.0249(13) -0.0032(11) 0.0077(12) C202 0.0233(11) 0.0448(14) 0.0577(16) 0.0052(12) 0.0078(11) -0.0016(10) C212 0.0458(14) 0.0328(13) 0.0520(15) 0.0054(11) 0.0171(12) 0.0013(10) S13 0.0257(3) 0.0349(3) 0.0251(3) 0.0013(2) 0.0054(2) -0.0005(2) S23 0.0351(3) 0.0264(3) 0.0288(3) -0.0018(2) 0.0135(2) -0.0057(2) C13 0.0295(12) 0.0610(16) 0.0321(12) -0.0107(11) 0.0038(10) -0.0062(11) C23 0.0267(12) 0.0565(15) 0.0430(14) -0.0150(12) 0.0084(10) -0.0106(10) C33 0.0368(13) 0.0363(12) 0.0460(14) -0.0093(10) 0.0170(11) -0.0136(10) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Rh1 C211 1.827(2) . ? Rh1 P1 2.3163(5) . ? Rh1 S23 2.3784(5) . ? Rh1 S13 2.3940(5) . ? Rh1 Rh2 3.0845(2) . ? P1 C121 1.8592(19) . ? P1 C131 1.891(2) . ? P1 C171 1.898(2) . ? O1 C211 1.145(3) . ? N1 C11 1.343(2) . ? N1 C51 1.349(2) . ? C11 C21 1.392(3) . ? C11 C121 1.509(3) . ? C21 C31 1.373(3) . ? C21 H21 0.9500 . ? C31 C41 1.378(3) . ? C31 H31 0.9500 . ? C41 C51 1.388(3) . ? C41 H41 0.9500 . ? C51 C61 1.490(3) . ? C61 C111 1.383(3) . ? C61 C71 1.393(3) . ? C71 C81 1.388(3) . ? C71 H71 0.9500 . ? C81 C91 1.359(3) . ? C81 H81 0.9500 . ? C91 C101 1.382(3) . ? C91 H91 0.9500 . ? C101 C111 1.388(3) . ? C101 H101 0.9500 . ? C111 H111 0.9500 . ? C121 H12A 0.9900 . ? C121 H12B 0.9900 . ? C131 C151 1.537(3) . ? C131 C141 1.538(3) . ? C131 C161 1.542(3) . ? C141 H14A 0.9800 . ? C141 H14B 0.9800 . ? C141 H14C 0.9800 . ? C151 H15A 0.9800 . ? C151 H15B 0.9800 . ? C151 H15C 0.9800 . ? C161 H16A 0.9800 . ? C161 H16B 0.9800 . ? C161 H16C 0.9800 . ? C171 C191 1.526(3) . ? C171 C201 1.541(3) . ? C171 C181 1.541(3) . ? C181 H18A 0.9800 . ? C181 H18B 0.9800 . ? C181 H18C 0.9800 . ? C191 H19A 0.9800 . ? C191 H19B 0.9800 . ? C191 H19C 0.9800 . ? C201 H20A 0.9800 . ? C201 H20B 0.9800 . ? C201 H20C 0.9800 . ? Rh2 C212 1.808(2) . ? Rh2 P2 2.3154(6) . ? Rh2 S13 2.3833(5) . ? Rh2 S23 2.3948(5) . ? P2 C122 1.844(2) . ? P2 C172 1.894(2) . ? P2 C132 1.898(2) . ? O2 C212 1.147(3) . ? N2 C12 1.339(3) . ? N2 C52 1.352(2) . ? C12 C22 1.386(3) . ? C12 C122 1.519(3) . ? C22 C32 1.386(3) . ? C22 H22 0.9500 . ? C32 C42 1.381(3) . ? C32 H32 0.9500 . ? C42 C52 1.387(3) . ? C42 H42 0.9500 . ? C52 C62 1.481(3) . ? C62 C112 1.388(3) . ? C62 C72 1.391(3) . ? C72 C82 1.389(3) . ? C72 H72 0.9500 . ? C82 C92 1.374(4) . ? C82 H82 0.9500 . ? C92 C102 1.373(4) . ? C92 H92 0.9500 . ? C102 C112 1.380(3) . ? C102 H102 0.9500 . ? C112 H112 0.9500 . ? C122 H12C 0.9900 . ? C122 H12D 0.9900 . ? C132 C152 1.538(3) . ? C132 C142 1.541(3) . ? C132 C162 1.544(3) . ? C142 H14D 0.9800 . ? C142 H14E 0.9800 . ? C142 H14F 0.9800 . ? C152 H15D 0.9800 . ? C152 H15E 0.9800 . ? C152 H15F 0.9800 . ? C162 H16D 0.9800 . ? C162 H16E 0.9800 . ? C162 H16F 0.9800 . ? C172 C192 1.532(3) . ? C172 C182 1.537(3) . ? C172 C202 1.540(3) . ? C182 H18D 0.9800 . ? C182 H18E 0.9800 . ? C182 H18F 0.9800 . ? C192 H19D 0.9800 . ? C192 H19E 0.9800 . ? C192 H19F 0.9800 . ? C202 H20D 0.9800 . ? C202 H20E 0.9800 . ? C202 H20F 0.9800 . ? S13 C13 1.831(2) . ? S23 C33 1.829(2) . ? C13 C23 1.516(3) . ? C13 H13A 0.9900 . ? C13 H13B 0.9900 . ? C23 C33 1.520(3) . ? C23 H23A 0.9900 . ? C23 H23B 0.9900 . ? C33 H33A 0.9900 . ? C33 H33B 0.9900 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C211 Rh1 P1 95.14(7) . . ? C211 Rh1 S23 87.41(7) . . ? P1 Rh1 S23 177.360(19) . . ? C211 Rh1 S13 170.17(7) . . ? P1 Rh1 S13 94.682(18) . . ? S23 Rh1 S13 82.762(18) . . ? C211 Rh1 Rh2 122.90(7) . . ? P1 Rh1 Rh2 128.523(14) . . ? S23 Rh1 Rh2 49.976(13) . . ? S13 Rh1 Rh2 49.633(13) . . ? C121 P1 C131 103.02(9) . . ? C121 P1 C171 100.98(9) . . ? C131 P1 C171 110.28(9) . . ? C121 P1 Rh1 116.16(6) . . ? C131 P1 Rh1 116.48(7) . . ? C171 P1 Rh1 108.75(6) . . ? C11 N1 C51 118.85(17) . . ? N1 C11 C21 122.21(18) . . ? N1 C11 C121 116.11(17) . . ? C21 C11 C121 121.61(17) . . ? C31 C21 C11 118.63(19) . . ? C31 C21 H21 120.7 . . ? C11 C21 H21 120.7 . . ? C21 C31 C41 119.5(2) . . ? C21 C31 H31 120.3 . . ? C41 C31 H31 120.3 . . ? C31 C41 C51 119.40(19) . . ? C31 C41 H41 120.3 . . ? C51 C41 H41 120.3 . . ? N1 C51 C41 121.35(18) . . ? N1 C51 C61 116.96(17) . . ? C41 C51 C61 121.68(18) . . ? C111 C61 C71 118.15(19) . . ? C111 C61 C51 120.64(18) . . ? C71 C61 C51 121.20(19) . . ? C81 C71 C61 120.5(2) . . ? C81 C71 H71 119.7 . . ? C61 C71 H71 119.7 . . ? C91 C81 C71 120.7(2) . . ? C91 C81 H81 119.7 . . ? C71 C81 H81 119.7 . . ? C81 C91 C101 119.7(2) . . ? C81 C91 H91 120.1 . . ? C101 C91 H91 120.1 . . ? C91 C101 C111 120.0(2) . . ? C91 C101 H101 120.0 . . ? C111 C101 H101 120.0 . . ? C61 C111 C101 120.9(2) . . ? C61 C111 H111 119.6 . . ? C101 C111 H111 119.6 . . ? C11 C121 P1 118.76(14) . . ? C11 C121 H12A 107.6 . . ? P1 C121 H12A 107.6 . . ? C11 C121 H12B 107.6 . . ? P1 C121 H12B 107.6 . . ? H12A C121 H12B 107.1 . . ? C151 C131 C141 108.44(18) . . ? C151 C131 C161 107.88(17) . . ? C141 C131 C161 108.14(18) . . ? C151 C131 P1 114.32(15) . . ? C141 C131 P1 110.63(14) . . ? C161 C131 P1 107.24(14) . . ? C131 C141 H14A 109.5 . . ? C131 C141 H14B 109.5 . . ? H14A C141 H14B 109.5 . . ? C131 C141 H14C 109.5 . . ? H14A C141 H14C 109.5 . . ? H14B C141 H14C 109.5 . . ? C131 C151 H15A 109.5 . . ? C131 C151 H15B 109.5 . . ? H15A C151 H15B 109.5 . . ? C131 C151 H15C 109.5 . . ? H15A C151 H15C 109.5 . . ? H15B C151 H15C 109.5 . . ? C131 C161 H16A 109.5 . . ? C131 C161 H16B 109.5 . . ? H16A C161 H16B 109.5 . . ? C131 C161 H16C 109.5 . . ? H16A C161 H16C 109.5 . . ? H16B C161 H16C 109.5 . . ? C191 C171 C201 109.76(18) . . ? C191 C171 C181 107.11(18) . . ? C201 C171 C181 107.66(17) . . ? C191 C171 P1 115.30(14) . . ? C201 C171 P1 109.35(14) . . ? C181 C171 P1 107.36(14) . . ? C171 C181 H18A 109.5 . . ? C171 C181 H18B 109.5 . . ? H18A C181 H18B 109.5 . . ? C171 C181 H18C 109.5 . . ? H18A C181 H18C 109.5 . . ? H18B C181 H18C 109.5 . . ? C171 C191 H19A 109.5 . . ? C171 C191 H19B 109.5 . . ? H19A C191 H19B 109.5 . . ? C171 C191 H19C 109.5 . . ? H19A C191 H19C 109.5 . . ? H19B C191 H19C 109.5 . . ? C171 C201 H20A 109.5 . . ? C171 C201 H20B 109.5 . . ? H20A C201 H20B 109.5 . . ? C171 C201 H20C 109.5 . . ? H20A C201 H20C 109.5 . . ? H20B C201 H20C 109.5 . . ? O1 C211 Rh1 173.4(2) . . ? C212 Rh2 P2 94.78(8) . . ? C212 Rh2 S13 89.33(8) . . ? P2 Rh2 S13 171.312(19) . . ? C212 Rh2 S23 171.13(8) . . ? P2 Rh2 S23 93.690(19) . . ? S13 Rh2 S23 82.642(18) . . ? C212 Rh2 Rh1 126.61(8) . . ? P2 Rh2 Rh1 122.036(14) . . ? S13 Rh2 Rh1 49.936(13) . . ? S23 Rh2 Rh1 49.512(13) . . ? C122 P2 C172 101.89(9) . . ? C122 P2 C132 102.47(10) . . ? C172 P2 C132 110.29(9) . . ? C122 P2 Rh2 113.10(7) . . ? C172 P2 Rh2 108.24(7) . . ? C132 P2 Rh2 119.41(8) . . ? C12 N2 C52 118.24(17) . . ? N2 C12 C22 122.30(18) . . ? N2 C12 C122 114.75(17) . . ? C22 C12 C122 122.82(19) . . ? C32 C22 C12 119.3(2) . . ? C32 C22 H22 120.4 . . ? C12 C22 H22 120.4 . . ? C42 C32 C22 118.8(2) . . ? C42 C32 H32 120.6 . . ? C22 C32 H32 120.6 . . ? C32 C42 C52 118.93(19) . . ? C32 C42 H42 120.5 . . ? C52 C42 H42 120.5 . . ? N2 C52 C42 122.41(19) . . ? N2 C52 C62 116.00(18) . . ? C42 C52 C62 121.59(18) . . ? C112 C62 C72 118.7(2) . . ? C112 C62 C52 119.78(19) . . ? C72 C62 C52 121.5(2) . . ? C82 C72 C62 120.2(2) . . ? C82 C72 H72 119.9 . . ? C62 C72 H72 119.9 . . ? C92 C82 C72 120.3(2) . . ? C92 C82 H82 119.9 . . ? C72 C82 H82 119.9 . . ? C102 C92 C82 119.8(2) . . ? C102 C92 H92 120.1 . . ? C82 C92 H92 120.1 . . ? C92 C102 C112 120.5(2) . . ? C92 C102 H102 119.8 . . ? C112 C102 H102 119.8 . . ? C102 C112 C62 120.5(2) . . ? C102 C112 H112 119.8 . . ? C62 C112 H112 119.8 . . ? C12 C122 P2 118.20(15) . . ? C12 C122 H12C 107.8 . . ? P2 C122 H12C 107.8 . . ? C12 C122 H12D 107.8 . . ? P2 C122 H12D 107.8 . . ? H12C C122 H12D 107.1 . . ? C152 C132 C142 107.84(18) . . ? C152 C132 C162 109.28(19) . . ? C142 C132 C162 107.8(2) . . ? C152 C132 P2 113.31(17) . . ? C142 C132 P2 107.62(15) . . ? C162 C132 P2 110.78(15) . . ? C132 C142 H14D 109.5 . . ? C132 C142 H14E 109.5 . . ? H14D C142 H14E 109.5 . . ? C132 C142 H14F 109.5 . . ? H14D C142 H14F 109.5 . . ? H14E C142 H14F 109.5 . . ? C132 C152 H15D 109.5 . . ? C132 C152 H15E 109.5 . . ? H15D C152 H15E 109.5 . . ? C132 C152 H15F 109.5 . . ? H15D C152 H15F 109.5 . . ? H15E C152 H15F 109.5 . . ? C132 C162 H16D 109.5 . . ? C132 C162 H16E 109.5 . . ? H16D C162 H16E 109.5 . . ? C132 C162 H16F 109.5 . . ? H16D C162 H16F 109.5 . . ? H16E C162 H16F 109.5 . . ? C192 C172 C182 109.10(19) . . ? C192 C172 C202 109.81(19) . . ? C182 C172 C202 106.17(17) . . ? C192 C172 P2 114.21(14) . . ? C182 C172 P2 107.17(13) . . ? C202 C172 P2 110.03(15) . . ? C172 C182 H18D 109.5 . . ? C172 C182 H18E 109.5 . . ? H18D C182 H18E 109.5 . . ? C172 C182 H18F 109.5 . . ? H18D C182 H18F 109.5 . . ? H18E C182 H18F 109.5 . . ? C172 C192 H19D 109.5 . . ? C172 C192 H19E 109.5 . . ? H19D C192 H19E 109.5 . . ? C172 C192 H19F 109.5 . . ? H19D C192 H19F 109.5 . . ? H19E C192 H19F 109.5 . . ? C172 C202 H20D 109.5 . . ? C172 C202 H20E 109.5 . . ? H20D C202 H20E 109.5 . . ? C172 C202 H20F 109.5 . . ? H20D C202 H20F 109.5 . . ? H20E C202 H20F 109.5 . . ? O2 C212 Rh2 173.0(2) . . ? C13 S13 Rh2 107.30(7) . . ? C13 S13 Rh1 103.82(8) . . ? Rh2 S13 Rh1 80.430(16) . . ? C33 S23 Rh1 105.38(8) . . ? C33 S23 Rh2 105.61(8) . . ? Rh1 S23 Rh2 80.512(16) . . ? C23 C13 S13 115.53(15) . . ? C23 C13 H13A 108.4 . . ? S13 C13 H13A 108.4 . . ? C23 C13 H13B 108.4 . . ? S13 C13 H13B 108.4 . . ? H13A C13 H13B 107.5 . . ? C13 C23 C33 114.2(2) . . ? C13 C23 H23A 108.7 . . ? C33 C23 H23A 108.7 . . ? C13 C23 H23B 108.7 . . ? C33 C23 H23B 108.7 . . ? H23A C23 H23B 107.6 . . ? C23 C33 S23 117.03(15) . . ? C23 C33 H33A 108.0 . . ? S23 C33 H33A 108.0 . . ? C23 C33 H33B 108.0 . . ? S23 C33 H33B 108.0 . . ? H33A C33 H33B 107.3 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C211 Rh1 P1 C121 -154.81(10) . . . . ? S13 Rh1 P1 C121 25.49(7) . . . . ? Rh2 Rh1 P1 C121 -14.57(7) . . . . ? C211 Rh1 P1 C131 -33.13(10) . . . . ? S13 Rh1 P1 C131 147.16(7) . . . . ? Rh2 Rh1 P1 C131 107.11(7) . . . . ? C211 Rh1 P1 C171 92.18(10) . . . . ? S13 Rh1 P1 C171 -87.52(7) . . . . ? Rh2 Rh1 P1 C171 -127.58(7) . . . . ? C51 N1 C11 C21 -1.4(3) . . . . ? C51 N1 C11 C121 175.51(17) . . . . ? N1 C11 C21 C31 2.6(3) . . . . ? C121 C11 C21 C31 -174.2(2) . . . . ? C11 C21 C31 C41 -1.1(3) . . . . ? C21 C31 C41 C51 -1.4(4) . . . . ? C11 N1 C51 C41 -1.2(3) . . . . ? C11 N1 C51 C61 179.99(17) . . . . ? C31 C41 C51 N1 2.6(3) . . . . ? C31 C41 C51 C61 -178.6(2) . . . . ? N1 C51 C61 C111 16.4(3) . . . . ? C41 C51 C61 C111 -162.4(2) . . . . ? N1 C51 C61 C71 -164.69(19) . . . . ? C41 C51 C61 C71 16.5(3) . . . . ? C111 C61 C71 C81 0.9(3) . . . . ? C51 C61 C71 C81 -178.0(2) . . . . ? C61 C71 C81 C91 -0.2(4) . . . . ? C71 C81 C91 C101 0.1(4) . . . . ? C81 C91 C101 C111 -0.7(4) . . . . ? C71 C61 C111 C101 -1.5(3) . . . . ? C51 C61 C111 C101 177.4(2) . . . . ? C91 C101 C111 C61 1.4(3) . . . . ? N1 C11 C121 P1 120.82(16) . . . . ? C21 C11 C121 P1 -62.2(2) . . . . ? C131 P1 C121 C11 -58.58(17) . . . . ? C171 P1 C121 C11 -172.61(15) . . . . ? Rh1 P1 C121 C11 69.99(16) . . . . ? C121 P1 C131 C151 -34.39(17) . . . . ? C171 P1 C131 C151 72.70(17) . . . . ? Rh1 P1 C131 C151 -162.76(13) . . . . ? C121 P1 C131 C141 -157.13(15) . . . . ? C171 P1 C131 C141 -50.04(18) . . . . ? Rh1 P1 C131 C141 74.50(16) . . . . ? C121 P1 C131 C161 85.15(15) . . . . ? C171 P1 C131 C161 -167.76(14) . . . . ? Rh1 P1 C131 C161 -43.22(16) . . . . ? C121 P1 C171 C191 67.99(18) . . . . ? C131 P1 C171 C191 -40.45(19) . . . . ? Rh1 P1 C171 C191 -169.31(14) . . . . ? C121 P1 C171 C201 -167.79(15) . . . . ? C131 P1 C171 C201 83.77(16) . . . . ? Rh1 P1 C171 C201 -45.09(16) . . . . ? C121 P1 C171 C181 -51.26(15) . . . . ? C131 P1 C171 C181 -159.70(14) . . . . ? Rh1 P1 C171 C181 71.44(14) . . . . ? C211 Rh1 Rh2 C212 138.05(14) . . . . ? P1 Rh1 Rh2 C212 7.40(10) . . . . ? S23 Rh1 Rh2 C212 -169.79(10) . . . . ? S13 Rh1 Rh2 C212 -49.93(10) . . . . ? C211 Rh1 Rh2 P2 12.10(9) . . . . ? P1 Rh1 Rh2 P2 -118.55(2) . . . . ? S23 Rh1 Rh2 P2 64.25(2) . . . . ? S13 Rh1 Rh2 P2 -175.88(2) . . . . ? C211 Rh1 Rh2 S13 -172.02(9) . . . . ? P1 Rh1 Rh2 S13 57.33(2) . . . . ? S23 Rh1 Rh2 S13 -119.86(2) . . . . ? C211 Rh1 Rh2 S23 -52.16(9) . . . . ? P1 Rh1 Rh2 S23 177.19(2) . . . . ? S13 Rh1 Rh2 S23 119.86(2) . . . . ? C212 Rh2 P2 C122 150.24(11) . . . . ? S23 Rh2 P2 C122 -27.11(7) . . . . ? Rh1 Rh2 P2 C122 -70.46(7) . . . . ? C212 Rh2 P2 C172 -97.65(10) . . . . ? S23 Rh2 P2 C172 85.01(7) . . . . ? Rh1 Rh2 P2 C172 41.65(8) . . . . ? C212 Rh2 P2 C132 29.58(11) . . . . ? S23 Rh2 P2 C132 -147.77(8) . . . . ? Rh1 Rh2 P2 C132 168.88(8) . . . . ? C52 N2 C12 C22 1.5(3) . . . . ? C52 N2 C12 C122 -174.41(17) . . . . ? N2 C12 C22 C32 -1.4(3) . . . . ? C122 C12 C22 C32 174.27(19) . . . . ? C12 C22 C32 C42 0.2(3) . . . . ? C22 C32 C42 C52 0.7(3) . . . . ? C12 N2 C52 C42 -0.6(3) . . . . ? C12 N2 C52 C62 -179.39(17) . . . . ? C32 C42 C52 N2 -0.5(3) . . . . ? C32 C42 C52 C62 178.22(19) . . . . ? N2 C52 C62 C112 36.7(3) . . . . ? C42 C52 C62 C112 -142.1(2) . . . . ? N2 C52 C62 C72 -144.38(19) . . . . ? C42 C52 C62 C72 36.8(3) . . . . ? C112 C62 C72 C82 0.6(3) . . . . ? C52 C62 C72 C82 -178.35(19) . . . . ? C62 C72 C82 C92 1.6(3) . . . . ? C72 C82 C92 C102 -1.9(3) . . . . ? C82 C92 C102 C112 0.1(4) . . . . ? C92 C102 C112 C62 2.1(3) . . . . ? C72 C62 C112 C102 -2.4(3) . . . . ? C52 C62 C112 C102 176.51(19) . . . . ? N2 C12 C122 P2 -138.30(16) . . . . ? C22 C12 C122 P2 45.8(3) . . . . ? C172 P2 C122 C12 176.85(15) . . . . ? C132 P2 C122 C12 62.68(17) . . . . ? Rh2 P2 C122 C12 -67.19(16) . . . . ? C122 P2 C132 C152 33.19(17) . . . . ? C172 P2 C132 C152 -74.68(17) . . . . ? Rh2 P2 C132 C152 159.05(13) . . . . ? C122 P2 C132 C142 -85.95(17) . . . . ? C172 P2 C132 C142 166.19(16) . . . . ? Rh2 P2 C132 C142 39.91(18) . . . . ? C122 P2 C132 C162 156.42(17) . . . . ? C172 P2 C132 C162 48.6(2) . . . . ? Rh2 P2 C132 C162 -77.72(18) . . . . ? C122 P2 C172 C192 -61.66(19) . . . . ? C132 P2 C172 C192 46.6(2) . . . . ? Rh2 P2 C172 C192 178.90(16) . . . . ? C122 P2 C172 C182 59.30(16) . . . . ? C132 P2 C172 C182 167.54(15) . . . . ? Rh2 P2 C172 C182 -60.14(15) . . . . ? C122 P2 C172 C202 174.32(15) . . . . ? C132 P2 C172 C202 -77.44(17) . . . . ? Rh2 P2 C172 C202 54.88(16) . . . . ? C212 Rh2 S13 C13 -116.30(12) . . . . ? S23 Rh2 S13 C13 59.92(9) . . . . ? Rh1 Rh2 S13 C13 101.60(9) . . . . ? C212 Rh2 S13 Rh1 142.10(8) . . . . ? S23 Rh2 S13 Rh1 -41.685(16) . . . . ? P1 Rh1 S13 C13 115.75(8) . . . . ? S23 Rh1 S13 C13 -63.59(8) . . . . ? Rh2 Rh1 S13 C13 -105.61(8) . . . . ? P1 Rh1 S13 Rh2 -138.640(16) . . . . ? S23 Rh1 S13 Rh2 42.023(16) . . . . ? C211 Rh1 S23 C33 -117.87(11) . . . . ? S13 Rh1 S23 C33 61.95(8) . . . . ? Rh2 Rh1 S23 C33 103.71(8) . . . . ? C211 Rh1 S23 Rh2 138.42(8) . . . . ? S13 Rh1 S23 Rh2 -41.763(16) . . . . ? P2 Rh2 S23 C33 126.48(8) . . . . ? S13 Rh2 S23 C33 -61.43(8) . . . . ? Rh1 Rh2 S23 C33 -103.44(8) . . . . ? P2 Rh2 S23 Rh1 -130.080(17) . . . . ? S13 Rh2 S23 Rh1 42.006(16) . . . . ? Rh2 S13 C13 C23 -9.5(2) . . . . ? Rh1 S13 C13 C23 74.61(19) . . . . ? S13 C13 C23 C33 -66.1(3) . . . . ? C13 C23 C33 S23 63.6(2) . . . . ? Rh1 S23 C33 C23 -70.33(18) . . . . ? Rh2 S23 C33 C23 13.90(19) . . . . ? _diffrn_measured_fraction_theta_max 1.000 _diffrn_reflns_theta_full 27.50 _diffrn_measured_fraction_theta_full 1.000 _refine_diff_density_max 0.319 _refine_diff_density_min -0.318 _refine_diff_density_rms 0.060 #===END